Radical mechanism in the elimination of 2-arylsulfinyl esters.
نویسندگان
چکیده
The mechanism of the dehydrosulfenylation of 2-arylsulfinyl esters was investigated. The reaction was found to follow a homolytic cleavage mechanism as verified by electrospray ionization tandem mass spectrometry and experimental work. Rearranged sulfoxides are obtained as byproduct during the elimination reaction.
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ورودعنوان ژورنال:
- The Journal of organic chemistry
دوره 77 11 شماره
صفحات -
تاریخ انتشار 2012